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Install a chatting program on your computer and start chatting with your friend online.I have cover most of the chatting program below. Additionally, Most of the chatting program below come with the choice of hundreds of plugins, icons, sounds and other content.
Miranda =The lite, faster, easier instant messenger with support for multiple protocols. Designed from the ground-up to be resource efficient while still providing a rich feature set, Miranda includes support for AIM, Jabber, ICQ, IRC, MSN, Yahoo, Gadu-Gadu and more.
MSN Messenger - Windows Live Messenger is the next-generation MSN Messenger. It has everything you already love about Messenger, and much more!
Yahoo Messenger - features including the ability to IM with Windows Live (MSN) users, Plug-Ins, Yahoo! 360, along with Soundboard and Soundtrack for all you free and premium voice users.and lot more..
Yahoo! Messenger for the Web =instant message from any web browser including anytime access to your contacts and message history.
Google Talk - You can talk to anyone else for free who's online and has the Google Talk client and send files to your contacts. There are no file size or bandwidth restrictions
QIP - QIP is a freeware program for online communication. It`s one of the most popular instant messengers. It is used by many thousands of users. QIP is for instant message delivery and feedback
Gaim=A multi-protocol Instant Messaging client that allows you to use all of your IM accounts at once. 
JAJC -A ICQ-like chat client designed to run in any Windows (32 bit) environment.Jabber is an open source instant messaging architecture being built on top of XML. Jabber clients have the capability to communicate with users of other instant messaging systems (AIM, ICQ, Yahoo, MSN, etc..) as well as other communication systems like IRC.
HydraIRC -
HydraIRC is a completely new IRC client that makes IRC a joy to use. Previously IRC has been only for the computer literate but HydraIRC makes IRC accessible to everyone and provides enough features to keep even the most demanding power-user happy.
Skype - Make free Skype-to-Skype calls - any time of day, any day of the week, anywhere in the world. 
VoipStunt -Free program that uses the latest technology to bring free and high-quality voice communications to people all over the world. When you use the free VoipStunt software, you can call regular phones in various popular destinations for free or call at an incredible low rate to any other phone on the planet.
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Talkative IRC - Stable and easy to use chat client. The IRC network is not a meetingplace for only the advanced users anymore.
IceChat - User friendly program that can be setup in a matter of a minutes. IceChat is capable of connecting to multiple servers and channels all at once, with ease, so you can easily chat with your friends in your favorite channels.
